Butylamine → HCID 20555088, compound

HRID 1391053Notes

Reaction equation

HRID 1391053 reaction equation
[CH2:1]([O:4][C:5]1[CH:10]=[CH:9][CH:8]=[C:7]([N+:11]([O-:13])=[O:12])[C:6]=1[N+:14]([O-])=O)[CH:2]=[CH2:3].[CH2:17](N)[CH2:18][CH2:19][CH3:20]>C(O)(C)C>[CH2:1]([O:4][C:5]1[CH:10]=[CH:9][CH:8]=[C:7]([N+:11]([O-:13])=[O:12])[C:6]=1[NH:14][CH2:17][CH2:18][CH2:19][CH3:20])[CH:2]=[CH2:3]

Participants

4

Reactant 2

HCID 8007ButylamineHCID 20555071HCID 20555071, compound

Product 1

HCID 20555088HCID 20555088, compound

Reagents, catalysts & solvents 1

HCID 3776IsopropanolSolvent

Procedure

A mixture of 9.0 g of 1-allyloxy-2,3-dinitrobenzene and 40 ml of n-butylamine in 400 ml of isopropanol is heated under reflux, and stirred, for two hours. After evaporating off the solvent and the excess n-butylamine under reduced pressure, the resulting oil is dried at 50°/0.01 mm Hg for 2 hours. The 1-allyloxy-2-butylamino-3-nitrobenzene which is thus obtained can be further used without purification.

Workup

  1. temperatureis heated
  2. temperatureunder reflux
  3. customAfter evaporating off the solvent
  4. dry with materialthe excess n-butylamine under reduced pressure, the resulting oil is dried at 50°/0.01 mm Hg for 2 hours

Sources & evidence

ORD record
ord-49a5690dfa0c4fe3ad9cbc0fe52a429c
Source dataset
uspto-grants-1979_02
Patent number
US04140789

Reaction notes

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