Methanol → HCID 13625903, compound

HRID 1393544Notes

Reaction equation

HRID 1393544 reaction equation
Cl[C:2]1[CH:3]=[CH:4][C:5]([N+:16]([O-:18])=[O:17])=[C:6]([NH:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=2[CH3:15])[CH:7]=1.[Na].[CH3:20][OH:21]>>[CH3:20][O:21][C:2]1[CH:3]=[CH:4][C:5]([N+:16]([O-:18])=[O:17])=[C:6]([NH:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=2[CH3:15])[CH:7]=1

Participants

4

Reactant 3

HCID 887MethanolHCID 5360545SodiumHCID 53269523HCID 53269523, compound

Product 1

HCID 13625903HCID 13625903, compound

Conditions

Temperature
0 °C

Procedure

1 g of 5-chloro-2-nitrophenyl-o-tolylamine was added to a solution of 1 g of sodium in 20 ml of methanol, and it was refluxed for 72 hours. Then, it is cooled to 0° C., and the crystalline product is suctioned off.

Workup

  1. temperaturewas refluxed for 72 hours

Sources & evidence

ORD record
ord-4a33b0244212464fb301ebca36b3a333
Source dataset
uspto-grants-2008_03
Patent number
US07345075B2

Reaction notes

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