Methanol → HCID 67366440, compound

HRID 1393547Notes

Reaction equation

HRID 1393547 reaction equation
Cl[C:2]1[CH:3]=[CH:4][C:5]([N+:16]([O-:18])=[O:17])=[C:6]([NH:8][C:9]2[CH:10]=[C:11]([CH3:15])[CH:12]=[CH:13][CH:14]=2)[CH:7]=1.[Na].[CH3:20][OH:21]>>[CH3:20][O:21][C:2]1[CH:3]=[CH:4][C:5]([N+:16]([O-:18])=[O:17])=[C:6]([NH:8][C:9]2[CH:10]=[C:11]([CH3:15])[CH:12]=[CH:13][CH:14]=2)[CH:7]=1

Participants

4

Reactant 3

HCID 887MethanolHCID 5360545SodiumHCID 53269524HCID 53269524, compound

Product 1

HCID 67366440HCID 67366440, compound

Conditions

Temperature
0 °C

Procedure

39 g of 5-chloro-2-nitrophenyl-m-tolylamine was added to a solution of 9 g of sodium in 670 ml of methanol, and it was refluxed for 72 hours. Then, it is cooled to 0° C., and the crystalline product is suctioned off.

Workup

  1. temperaturewas refluxed for 72 hours

Sources & evidence

ORD record
ord-c5586b27f96f44ce9eb983bc2d13291d
Source dataset
uspto-grants-2008_03
Patent number
US07345075B2

Reaction notes

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