Lithium hydroxide, monohydrate → HCID 10005063, compound

HRID 1394538Notes

Reaction equation

HRID 1394538 reaction equation
[CH3:1][C:2]1([CH3:33])[C:11]2[CH:10]=[C:9]([Se:12][C:13]3[CH:18]=[CH:17][C:16](/[CH:19]=[CH:20]/[C:21]([O:23]CC)=[O:22])=[CH:15][CH:14]=3)[CH:8]=[CH:7][C:6]=2[C:5]([C:26]2[CH:31]=[CH:30][C:29]([CH3:32])=[CH:28][CH:27]=2)=[CH:4][CH2:3]1.O.[OH-].[Li+]>>[CH3:1][C:2]1([CH3:33])[C:11]2[CH:10]=[C:9]([Se:12][C:13]3[CH:18]=[CH:17][C:16](/[CH:19]=[CH:20]/[C:21]([OH:23])=[O:22])=[CH:15][CH:14]=3)[CH:8]=[CH:7][C:6]=2[C:5]([C:26]2[CH:27]=[CH:28][C:29]([CH3:32])=[CH:30][CH:31]=2)=[CH:4][CH2:3]1

Participants

3

Reactant 2

HCID 168937Lithium hydroxide, monohydrateHCID 86601150HCID 86601150, compound

Product 1

HCID 10005063HCID 10005063, compound

Procedure

In a manner similar to that of Example 1g, by reacting 0.11 g (0.23 mmol) of ethyl (E)-3-[4-(8,8-dimethyl-5-p-tolyl-7,8-dihydro-2-naphthylselanyl)phenyl]acrylate with 0.11 g (2.6 mmol) of lithium hydroxide hydrate, a yellow solid is obtained (0.08 g; yield=78%).

Workup

  1. customa yellow solid is obtained (0.08 g; yield=78%)

Sources & evidence

ORD record
ord-6df1837834194006be30e46a27b2954d
Source dataset
uspto-grants-2008_03
Patent number
US07348449B2

Reaction notes

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