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HRID1394968

反应详情

EQUATION

反应方程式

HRID 1394968 的结构方程式

REACTANTS

反应物

2
结构：CC(=O)c1ccc(Br)cc1
HCID7466

Ethanone, 1-(4-bromophenyl)-

C8H7BrO

结构：CC(C)(C)OC(=O)NC(CCC(=O)Oc1ccccc1)C(=O)O
HCID178453484

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)c1ccc(C(CCC(=O)Oc2ccccc2)NC(=O)OC(C)(C)C)cc1
HCID178466297

未命名化合物

收率 77%

AUXILIARIES

试剂、催化剂与溶剂

5
结构：O=C([O-])[O-].[Cs+].[Cs+]
试剂HCID10796

Cesium carbonate

CCs2O3

结构：CC(C)(C)c1ccnc(-c2cc(C(C)(C)C)ccn2)c1
催化剂HCID4249187

未命名化合物

结构：COCCOC.[Cl][Ni][Cl]
催化剂HCID15773433

未命名化合物

结构：CC(C)(C)c1ccn2->[Ir+]34(c5cc(F)cc(F)c5-c5ccc(C(F)(F)F)cn->35)(c3cc(F)cc(F)c3-c3ccc(C(F)(F)F)cn->43)<-n3ccc(C(C)(C)C)cc3-c2c1.F[P-](F)(F)(F)(F)F
催化剂HCID178441129

未命名化合物

结构：CN(C)C=O
溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

CONDITIONS

反应条件

温度
23 °C

PROCEDURE

实验过程

Prior to irradiation, the reaction mixture was degassed by bubbling argon for 20 minutes

WORKUP

后处理

  1. additiondiluted with saturated aqueous NaHCO3
  2. addition未记录说明
  3. addition未记录说明
  4. addition未记录说明
  5. extractionextracted with Et2O (3 x 100 mL) · 保留 organic
  6. washwashed with water and brine
  7. dry with materialdried over MgSO4
  8. concentrationconcentrated in vacuo
  9. flash chromatographyFluka, 230-400 mesh, solvent system: 20% ethyl acetate/hexane