Allyl chloride → HCID 86736967, compound

HRID 1395007Notes

Reaction equation

HRID 1395007 reaction equation
[OH-].[Na+].[CH2:3]([Cl:6])[CH:4]=[CH2:5].[C:7](#[N:10])[CH:8]=[CH2:9].S(OOS([O-])(=O)=O)([O-])(=O)=[O:12].[K+].[K+]>O>[C:7](#[N:10])[CH:8]=[CH2:9].[CH2:3]([OH:12])[CH:4]=[CH2:5].[CH2:3]([Cl:6])[CH:4]=[CH2:5]

Participants

6

Reactant 4

HCID 7850Allyl chlorideHCID 7855AcrylonitrileHCID 14798Sodium HydroxideHCID 24412Potassium Persulfate

Product 1

HCID 86736967HCID 86736967, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

About 10 parts by weight of fine granular silica, 2.5 parts by weight of sodium hydroxide flakes and 2 parts by weight of water are mixed then heated at 90 degrees to 100 degrees C. until the water evaporates, thereby producing an activated silica. 30 parts by weight of allyl chloride, 3 parts by weight of acrylonitrile, 12 parts by weight of water and 0.2 parts by weight of potassium persulfate are mixed then agitated at a temperature just below the boiling temperature of the reactants at ambient pressure for 1 to 12 hours, thereby producing a white, solid poly (allyl chloride allyl alcohol acrylonitrile) copolymer.

Workup

  1. temperaturethen heated at 90 degrees to 100 degrees C
  2. customuntil the water evaporates
  3. customproducing an activated silica

Sources & evidence

ORD record
ord-c6e50cd43a04401297d3a16b0b30b29a
Source dataset
uspto-grants-1980_05
Patent number
US04201702

Reaction notes

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