Hydrochloric Acid → HCID 131711750, compound

HRID 1395130Notes

Reaction equation

HRID 1395130 reaction equation
[C:1]([CH2:3][CH2:4][CH2:5][S:6][C:7](=[S:17])[NH:8][CH2:9][C:10]1[CH:15]=[CH:14][C:13]([Cl:16])=[CH:12][CH:11]=1)#[N:2].Cl.[OH2:19]>>[C:1]([CH2:3][CH2:4][CH2:5][S:6][C:7](=[S:17])[NH:8][CH2:9][C:10]1[CH:11]=[CH:12][C:13]([Cl:16])=[CH:14][CH:15]=1)(=[O:19])[NH2:2]

Participants

4

Reactant 3

HCID 313Hydrochloric AcidHCID 962WaterHCID 85930160HCID 85930160, compound

Product 1

HCID 131711750HCID 131711750, compound

Procedure

29.2 G. of 3-cyanopropyl(p-chlorobenzyl)dithiocarbamate were suspended in 150 ml. of concentrated hydrochloric acid and stirred at room temperature for 2 hours. The mixture was diluted with water and extracted with ethyl acetate. After washing, drying and concentration of the ethyl acetate phases, 18.1 g. of 3-carbamoylpropyl)p-chlorobenzyl)dithiocarbamate were crystallized from ethyl acetate/diisopropyl ether; melting point 123°-125° C.

Workup

  1. extractionextracted with ethyl acetate
  2. washAfter washing
  3. customdrying
  4. customof 3-carbamoylpropyl)p-chlorobenzyl)dithiocarbamate were crystallized from ethyl acetate/diisopropyl ether

Sources & evidence

ORD record
ord-f3071170fd414697a589444960c90387
Source dataset
uspto-grants-1980_05
Patent number
US04202832

Reaction notes

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