Chloroform → 1-Hexadecanesulfonyl chloride

HRID 1395342Notes

Reaction equation

HRID 1395342 reaction equation
[Cl:1]C1C=CC(N)=CC=1[N+]([O-])=O.C(Cl)(Cl)Cl.ClC1C=CC(N[S:24]([CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH3:42])(=[O:26])=[O:25])=CC=1[N+]([O-])=O>N1C=CC=CC=1>[CH2:27]([S:24]([Cl:1])(=[O:26])=[O:25])[CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH3:42]

Participants

5

Reactant 3

HCID 6212ChloroformHCID 124774-Chloro-3-nitroanilineHCID 1130451-Hexadecanesulfonamide, N-(4-chloro-3-nitrophenyl)-

Product 1

HCID 969231-Hexadecanesulfonyl chloride

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

Hexadecanesulfonylchloride, which was prepared by the method as described in J. M. Sprague, et al., J. Amer. Chem. Soc., Vol. 59, page 1837 (1937), was reacted with 2-chloro-5-aminonitrobenzene in a chloroform solution in the presence of pyridine to prepare 2-chloro-5-hexadecanesulfonamidonitrobenzene.

Sources & evidence

ORD record
ord-5355f19072274c93ae6b27039e772a72
Source dataset
uspto-grants-1980_05
Patent number
US04203768

Reaction notes

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