Dimethylformamide → HCID 13255940, compound

HRID 1395343Notes

Reaction equation

HRID 1395343 reaction equation
[CH3:1][O:2][C:3](=[O:26])[CH:4]([O:6][C:7]1[CH:12]=[C:11]([O:13][C:14]2[CH:19]=[CH:18][C:17]([C:20]([F:23])([F:22])[F:21])=[CH:16][C:15]=2[Cl:24])[CH:10]=[CH:9][C:8]=1Br)[CH3:5].[CH3:27][N:28](C)C=O>>[CH3:1][O:2][C:3](=[O:26])[CH:4]([O:6][C:7]1[CH:12]=[C:11]([O:13][C:14]2[CH:19]=[CH:18][C:17]([C:20]([F:23])([F:22])[F:21])=[CH:16][C:15]=2[Cl:24])[CH:10]=[CH:9][C:8]=1[C:27]#[N:28])[CH3:5]

Participants

3

Reactant 2

HCID 6228DimethylformamideHCID 13186121HCID 13186121, compound

Product 1

HCID 13255940HCID 13255940, compound

Procedure

A 10 g of methyl-α-[2-bromo-5-(2-chloro-4-trifluoromethyl phenoxy)phenoxy]propionate produced in Example 1 was dissolved in 15 ml of dimethyl formamide, and 2.4 g of cuprous cyanide was added to the solution and the reaction was conducted under reflux condition with stirring the mixture for 5 hours.

Workup

  1. temperatureunder reflux condition

Sources & evidence

ORD record
ord-8d4c696ccec248919529e0dba65f7db8
Source dataset
uspto-grants-1980_05
Patent number
US04203758

Reaction notes

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