Dimethylformamide → HCID 20339002, compound

HRID 1395346Notes

Reaction equation

HRID 1395346 reaction equation
[CH2:1]([O:3][C:4](=[O:28])[CH:5]([O:7][C:8]1[CH:13]=[C:12]([O:14][C:15]2[C:20]([Cl:21])=[CH:19][C:18]([C:22]([F:25])([F:24])[F:23])=[CH:17][C:16]=2[Cl:26])[CH:11]=[CH:10][C:9]=1Br)[CH3:6])[CH3:2].[CH3:29][N:30](C)C=O>>[CH2:1]([O:3][C:4](=[O:28])[CH:5]([O:7][C:8]1[CH:13]=[C:12]([O:14][C:15]2[C:20]([Cl:21])=[CH:19][C:18]([C:22]([F:25])([F:24])[F:23])=[CH:17][C:16]=2[Cl:26])[CH:11]=[CH:10][C:9]=1[C:29]#[N:30])[CH3:6])[CH3:2]

Participants

3

Reactant 2

HCID 6228DimethylformamideHCID 20339012HCID 20339012, compound

Product 1

HCID 20339002HCID 20339002, compound

Procedure

A 15 g of ethyl-α-[2-bromo-5-(2,6-dichloro-4-trifluoromethyl phenoxy) phenoxy]propionate produced in Example 7 was dissolved in 25 ml of dimethylformamide. A 3 g of cuprous cyanide was added to the solution and the reaction was conducted under reflux condition for 4 hours with stirring the mixture.

Workup

  1. temperatureunder reflux condition for 4 hours

Sources & evidence

ORD record
ord-9f0cfa3b27754203b23c76a8621c1f55
Source dataset
uspto-grants-1980_05
Patent number
US04203758

Reaction notes

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