反应详情

4-Hydroxy-3-(2-pyridylazo)-1-naphthalenesulfonic acid (110 g) was added to pyridine (350 ml) followed by benzoyl chloride (250 ml). Triethylamine (100 ml) was added slowly and the reaction mixture got warm. After 1 hour the mixture was diluted with five times its volume of acetone and filtered. The product was washed with acetone and allowed to suck dry. It was dissolved in water (minimum volume) and neutralized with hydrochloric acid. After filtration, the product was washed with acetone and ether. Yield 120 g (83 percent).

1. temperaturethe reaction mixture got warm
2. filtrationfiltered
3. washThe product was washed with acetone
4. customto suck dry
5. dissolutionIt was dissolved in water (minimum volume)
6. filtrationAfter filtration
7. washthe product was washed with acetone and ether