Methyl iodide → HCID 20337872, compound

HRID 1395652Notes

Reaction equation

HRID 1395652 reaction equation
[C:1]1([C:7]([C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)=[C:8]2[CH2:17][CH2:16][N:15]3[CH:10]([CH2:11][CH2:12][CH2:13][CH2:14]3)[CH2:9]2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH3:24][I:25]>CC(C)=O>[CH3:24][I:25].[C:1]1([C:7]([C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)=[C:8]2[CH2:17][CH2:16][N:15]3[CH:10]([CH2:11][CH2:12][CH2:13][CH2:14]3)[CH2:9]2)[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

4

Reactant 2

HCID 6328Methyl iodideHCID 12519326HCID 12519326, compound

Product 1

HCID 20337872HCID 20337872, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

In 10 ml. of acetone was dissolved 0.1 g. of 2-(diphenylmethylene)quinolizidine. After 1.0 ml. of methyl iodide was added to the solution, the mixture was stirred at room temperature of 24 hrs. The precipitated crystals were removed by filtration and recrystallized from methanol to give 0.1 g. of colorless needles having a melting point of 280° to 282° C.(decomposed).

Workup

  1. customThe precipitated crystals were removed by filtration
  2. customrecrystallized from methanol
  3. customto give 0.1 g

Sources & evidence

ORD record
ord-5c7eb9a905ef47b2923794a89f4902e0
Source dataset
uspto-grants-1980_05
Patent number
US04205074

Reaction notes

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