Methyl iodide → HCID 20337878, compound

HRID 1395657Notes

Reaction equation

HRID 1395657 reaction equation
[S:1]1[CH:5]=[CH:4][CH:3]=[C:2]1[C:6]([C:17]1[S:18][CH:19]=[CH:20][CH:21]=1)=[C:7]1[CH:16]2[N:11]([CH2:12][CH2:13][CH2:14][CH2:15]2)[CH2:10][CH2:9][CH2:8]1.[CH3:22][I:23]>CC(C)=O>[CH3:22][I:23].[S:1]1[CH:5]=[CH:4][CH:3]=[C:2]1[C:6]([C:17]1[S:18][CH:19]=[CH:20][CH:21]=1)=[C:7]1[CH:16]2[N:11]([CH2:12][CH2:13][CH2:14][CH2:15]2)[CH2:10][CH2:9][CH2:8]1

Participants

4

Reactant 2

HCID 6328Methyl iodideHCID 12519300HCID 12519300, compound

Product 1

HCID 20337878HCID 20337878, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

To a solution of 0.3 g. of 1-(dithien-2-ylmethylene)-quinolizidine in 5 ml. of anhydrous acetone was added 1 ml. of methyl iodide. The mixture was stirred at room temperature for 1 hr. The formed crystals were collected by filtration. By recrystallizing from isopropanol, 0.3 g. of light brown needles having a melting point of 284°-285° C. (decompd.) were obtained.

Workup

  1. filtrationThe formed crystals were collected by filtration
  2. customBy recrystallizing from isopropanol, 0.3 g
  3. customwere obtained

Sources & evidence

ORD record
ord-f8a38c800e8d458aaee13cbaa961e6cd
Source dataset
uspto-grants-1980_05
Patent number
US04205074

Reaction notes

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