Perbenzoic acid → (2-Ethoxycarbonyloxy-5-octanoylbenzoyl)benzoyl peroxide

HRID 1398278Notes

Reaction equation

[CH2:1]([O:3][C:4]([O:6][C:7]1[CH:15]=[CH:14][C:13]([C:16](=[O:24])[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23])=[CH:12][C:8]=1[C:9](Cl)=[O:10])=[O:5])[CH3:2].[CH:25]1[C:30]([C:31]([O:33][OH:34])=[O:32])=[CH:29][CH:28]=[CH:27][CH:26]=1>>[CH2:1]([O:3][C:4]([O:6][C:7]1[CH:15]=[CH:14][C:13]([C:16](=[O:24])[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23])=[CH:12][C:8]=1[C:9]([O:34][O:33][C:31](=[O:32])[C:30]1[CH:25]=[CH:26][CH:27]=[CH:28][CH:29]=1)=[O:10])=[O:5])[CH3:2]

Participants

Reactant 2

HCID 523077Perbenzoic acid

HCID 866802402-Ethoxycarbonyloxy-5-octanoylbenzoyl chloride

Product 1

HCID 53253035(2-Ethoxycarbonyloxy-5-octanoylbenzoyl)benzoyl peroxideYield 26%

Procedure

In a manner similar to that of Example 1-4, starting with 5.79 g (16.3 mmol) of 2-ethoxycarbonyloxy-5-octanoylbenzoyl chloride and 3.38 g (24.5 mmol) of perbenzoic acid (prepared as described in Example 1-3), 2 g of (2-ethoxycarbonyloxy-5-octanoyl)benzoyl peroxide are obtained in the form of a colourless oil in a yield of 26%.

Workup

customare obtained in the form of a colourless oil in a yield of 26%

Sources & evidence

ORD record: ord-dc16f8289a8f48ac890ba5188e3ab0b3
Source dataset: uspto-grants-2014_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08901357B2

Reaction notes

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