Methyl iodide → HCID 178456313, compound

HRID 1399406Notes

Reaction equation

HRID 1399406 reaction equation
[CH2:1]([N:4]1[CH:8]=[C:7]([CH2:9][Si:10]([CH3:13])([CH3:12])[CH3:11])[N:6]=[N:5]1)[CH2:2][CH3:3].[I:14][CH3:15]>C(#N)C>[I-:14].[CH3:15][N+:6]1[C:7]([CH2:9][Si:10]([CH3:11])([CH3:13])[CH3:12])=[CH:8][N:4]([CH2:1][CH2:2][CH3:3])[N:5]=1

Participants

4

Reactant 2

HCID 6328Methyl iodideHCID 1317321271-propyl-4-((trimethylsilyl)methyl)-1H-1,2,3-triazole

Product 1

HCID 178456313HCID 178456313, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

1-propyl-4-((trimethylsilyl)methyl)-1H-1,2,3-triazole and excess iodomethane were added to a vial. The reaction was heated for 19.5 hours and 5 mL ACN was added. The reaction was heated for another 2 hours. The precipitate was filtered, rinsed with ether and dried in vacuo overnight. The following 3-methyl-1-propyl-4-((trimethylsilyl)methyl)-1H-1,2,3-triazol-3-ium iodide structure was confirmed:

Workup

  1. temperatureThe reaction was heated for 19.5 hours
  2. temperatureThe reaction was heated for another 2 hours
  3. filtrationThe precipitate was filtered
  4. washrinsed with ether
  5. customdried in vacuo overnight

Sources & evidence

ORD record
ord-d6a1de97a30c4e5790593d24fd7dbf69
Source dataset
uspto-grants-2014_12
Patent number
US08906135B1

Reaction notes

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