Diethyl Malonate → HCID 66759493, compound

HRID 1402954Notes

Reaction equation

[CH:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[C:11](=[O:24])[CH:12]=[CH:13][C:14]1[CH:23]=[CH:22][C:21]2[C:16](=[CH:17][CH:18]=[CH:19][CH:20]=2)[CH:15]=1.[C:25]([O:33][CH2:34][CH3:35])(=[O:32])[CH2:26][C:27]([O:29][CH2:30][CH3:31])=[O:28]>>[CH:15]1[C:16]2[C:21](=[CH:20][CH:19]=[CH:18][CH:17]=2)[CH:22]=[CH:23][C:14]=1[CH:13]([CH:26]([C:27]([O:29][CH2:30][CH3:31])=[O:28])[C:25]([O:33][CH2:34][CH3:35])=[O:32])[CH2:12][C:11]([C:2]1[CH:3]=[CH:4][C:5]2[C:10](=[CH:9][CH:8]=[CH:7][CH:6]=2)[CH:1]=1)=[O:24]

Participants

Reactant 2

HCID 7761Diethyl Malonate

HCID 2794958HCID 2794958, compound

Product 1

HCID 66759493HCID 66759493, compound

Procedure

By a procedure similar to that of example 1.59.2, starting from 1,3-di(2-naphthalenyl)prop-2-en-1-one and diethyl malonate, diethyl 2-(1,3-di(2-naphthalenyl)-3-oxopropyl)malonate was obtained as colourless solid.

Sources & evidence

ORD record: ord-231cec658fb4411b906f4a3e96c255d0
Source dataset: uspto-grants-2014_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08912186B2

Reaction notes

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