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HRID1406275

反应详情

EQUATION

反应方程式

HRID 1406275 的结构方程式

REACTANTS

反应物

4
结构：COc1ccc(F)cc1C(C)=O
HCID2737356

1-(5-Fluoro-2-methoxyphenyl)ethanone

C9H9FO2

结构：C[C@@H]1[C@@H](B(Cl)[C@H]2C[C@@H]3C[C@H]([C@@H]2C)C3(C)C)C[C@@H]2C[C@H]1C2(C)C
HCID13515837

Chlorobis(2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)borane

C20H34BCl

结构：COc1ccc(F)cc1[C@H](C)O
HCID14928684

未命名化合物

结构：C[C@@H]1C2CCC(C[C@H]1B(Cl)[C@@H]1CC3CCC([C@H]1C)C3(C)C)C2(C)C
HCID16212015

未命名化合物

PRODUCTS

生成物

1
结构：COc1ccc(F)cc1[C@@H](C)O
HCID26597266

未命名化合物

PROCEDURE

实验过程

The title compound was prepared, according to the method used to make (S)-1-(5-fluoro-2-methoxy-phenyl)-ethanol from 1-(5-fluoro-2-methoxy-phenyl)-ethanone (see H. C. Brown, Tet. Letts., 35 (14), 2141-4, 1994) except that (+)-DIP-Chloride™ was used instead of (−)-DIP-Chloride™, as a white crystalline solid (63%).