Ammonium Chloride → HCID 86660395, compound

HRID 1406518Notes

Reaction equation

HRID 1406518 reaction equation
[Cl:1][C:2]1[N:7]=[C:6]([NH:8][C:9](=[O:21])[C:10]2[CH:15]=[CH:14][C:13]([NH:16][CH3:17])=[C:12]([N+:18]([O-])=O)[CH:11]=2)[CH:5]=[CH:4][CH:3]=1.[NH4+].[Cl-]>C(O)C.[Fe]>[NH2:18][C:12]1[CH:11]=[C:10]([CH:15]=[CH:14][C:13]=1[NH:16][CH3:17])[C:9]([NH:8][C:6]1[CH:5]=[CH:4][CH:3]=[C:2]([Cl:1])[N:7]=1)=[O:21]

Participants

5

Reactant 2

HCID 25517Ammonium ChlorideHCID 86660394HCID 86660394, compound

Product 1

HCID 86660395HCID 86660395, compound

Reagents, catalysts & solvents 2

HCID 23925IronCatalystHCID 702EthanolSolvent

Procedure

Prepared analogously to example 323c from N-(6-chloro-pyridin-2-yl)-4-methylamino-3-nitro-benzamide, iron powder and sat. NH4Cl solution in ethanol.

Sources & evidence

ORD record
ord-2ba7ea4e864d4fb2be11585e47dae4aa
Source dataset
uspto-grants-2014_12
Patent number
US08916599B2

Reaction notes

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