HCID 67230764, compound → HCID 67230257, compound

HRID 1406522Notes

Reaction equation

HRID 1406522 reaction equation
[Br:1][C:2]1[CH:3]=[C:4]([CH:9]=[C:10]([N+:14]([O-])=O)[C:11]=1[NH:12][CH3:13])[C:5]([O:7][CH3:8])=[O:6]>C(O)(=O)C.C(O)C.[Fe]>[NH2:14][C:10]1[CH:9]=[C:4]([CH:3]=[C:2]([Br:1])[C:11]=1[NH:12][CH3:13])[C:5]([O:7][CH3:8])=[O:6]

Participants

5

Reactant 1

HCID 67230764HCID 67230764, compound

Product 1

HCID 67230257HCID 67230257, compound

Reagents, catalysts & solvents 3

HCID 23925IronCatalystHCID 176Acetic AcidSolventHCID 702EthanolSolvent

Procedure

Prepared analogously to example 91a from methyl 3-bromo-4-(methylamino)-5-nitrobenzoate using iron powder in acetic acid and ethanol.

Sources & evidence

ORD record
ord-d878635f466f4984a6d294873d6b93c5
Source dataset
uspto-grants-2014_12
Patent number
US08916599B2

Reaction notes

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