Methane → HCID 20293161, compound

HRID 1413075Notes

Reaction equation

HRID 1413075 reaction equation
C([O:8][C:9]1[C:18]2[O:17][CH2:16][CH2:15][O:14][C:13]=2[C:12]([CH2:19]O)=[CH:11][CH:10]=1)C1C=CC=CC=1.C>[Pd]>[OH:8][C:9]1[C:18]2[O:17][CH2:16][CH2:15][O:14][C:13]=2[C:12]([CH3:19])=[CH:11][CH:10]=1

Participants

4

Reactant 2

HCID 297MethaneHCID 20293150HCID 20293150, compound

Product 1

HCID 20293161HCID 20293161, compound

Reagents, catalysts & solvents 1

HCID 23938PalladiumCatalyst

Procedure

A solution of 14.7 g (0.05 mole) of 5-benzyloxy-8-hydroxymethyl-1,4-benzodioxane (XIp) code number 760 701, crude, non-crystallized, in 300 ml of absolute alcohol was hydrogenolysed at room pressure and temperature, in the presence of 3 g of palladium on 5% charcoal. Once the absorption of hydrogen was completed, the catalyst was filtered and the solvent was evaporated. A liquid was obtained.

Workup

  1. customOnce the absorption of hydrogen
  2. filtrationthe catalyst was filtered
  3. customthe solvent was evaporated
  4. customA liquid was obtained

Sources & evidence

ORD record
ord-568b04880f9848fe9a7448b67f454d55
Source dataset
uspto-grants-1981_02
Patent number
US04248788

Reaction notes

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