反应详情

In a preferred embodiment of the present process for producing triphenylphosphine, about 1 part by weight of triphenylphosphine oxide in about 2 to about 3 parts by weight of chloroform is chlorinated with phosgene to produce a triphenylphosphine dichloride-chloroform adduct solution. The solution is adjusted (concentrated or diluted) by a known procedure to one having about 10 to about 20% by weight triphenylphosphine dichloride-chloroform adduct in chloroform. The resulting solution is hydrogenated at a pressure of about 100 bar of hydrogen and at a temperature of about 190° C. to about 195° C. to form the desired triphenylphosphine.