O-Allylhydroxylamine → HCID 178460154, compound

HRID 1413316Notes

Reaction equation

HRID 1413316 reaction equation
[C:1]([CH:6]1[C:11](=[O:12])[CH2:10][CH:9]([CH2:13][CH:14]([S:16]([CH2:18][CH3:19])=[O:17])[CH3:15])[CH2:8][C:7]1=[O:20])(=O)[CH2:2][CH2:3][CH3:4].[CH2:21]([O:24][NH2:25])[CH:22]=[CH2:23]>C(O)C>[CH2:21]([O:24][NH:25][C:1](=[C:6]1[C:11](=[O:12])[CH2:10][CH:9]([CH2:13][CH:14]([S:16]([CH2:18][CH3:19])=[O:17])[CH3:15])[CH2:8][C:7]1=[O:20])[CH2:2][CH2:3][CH3:4])[CH:22]=[CH2:23]

Participants

4

Reactant 2

HCID 420841O-AllylhydroxylamineHCID 20291509HCID 20291509, compound

Product 1

HCID 178460154HCID 178460154, compoundYield 67.6%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

6 g of 2-butyryl-5-(2-ethylsulfinylpropyl)-cyclohexane-1,3-dione was dissolved in 30 ml of ethanol. To the solution was added 1.6 g of allyloxyamine and the resulting solution was stirred at room temperature for 15 hours. After completion of the reaction, the reaction solution was treated as in Example 1 to obtain 4.8 g of the desired compound as colorless oily material.

Workup

  1. customAfter completion of the reaction
  2. additionthe reaction solution was treated as in Example 1

Sources & evidence

ORD record
ord-966c489c6edb4d61806134dae5b8467b
Source dataset
uspto-grants-1981_02
Patent number
US04249937

Reaction notes

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