Butanal → HCID 20700556, compound

HRID 1413387Notes

Reaction equation

HRID 1413387 reaction equation
[CH:1](=[O:5])[CH2:2][CH2:3][CH3:4]>FC(F)(F)C([O-])=O.[Ru+3].FC(F)(F)C([O-])=O.FC(F)(F)C([O-])=O.[Ru](Cl)(Cl)Cl>[CH2:1]([O:5][CH:2]([CH:3]([O:5][CH2:1][CH2:2][CH2:3][CH3:4])[CH3:4])[CH3:1])[CH2:2][CH2:3][CH3:4]

Participants

4

Reactant 1

HCID 261Butanal

Product 1

HCID 20700556HCID 20700556, compound

Reagents, catalysts & solvents 2

HCID 61850Ruthenium trichlorideCatalystHCID 23468319HCID 23468319, compoundCatalyst

Procedure

Example 18 is repeated, while using 1 m.mole ruthenium trifluoroacetate instead of 1 m.mole ruthenium trichloride. 18 m.moles butanal and 46 m.moles dibutoxybutane have been formed. No butyric acid is present.

Sources & evidence

ORD record
ord-e3bfd9189700437798014bd76cfde4a9
Source dataset
uspto-grants-1981_02
Patent number
US04250121

Reaction notes

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