HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzoic Acid → HCID 12791329, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzoic Acid | HCID 243 | — |
| Reactant | 1-Methoxyethane-1,1-diol | HCID 13755109 | — |
| Product | HCID 12791329 | HCID 12791329 | 965.7% |
Reaction Steps
88.0 g (1.0 mol) of cyclobutane-cis-1,2-diol, 120.0 g (1.0 mol) of orthoacetic acid methyl ester and 10.0 g of benzoic acid are heated from 80° to 120° C. in the course of 3 hours. Methanol which forms is distilled off continuously. Fractional distillation gives 114.0 g (79%) of 3-methoxy-3-methyl-2,4-dioxa-bicyclo[3,2,0]heptane (stereoisomer mixture) of boiling point12 52°-53°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04252738 |
| Source dataset | uspto-grants-1981_02 |
| ORD ID | ord-005ecff03a524a30a978081bb1407e40 |
| Source note | uspto-grants-1981_02 |