1,3-Propanediamine → 1,3-Propanediamine

HRID 1414159Notes

Reaction equation

HRID 1414159 reaction equation
[H][H].[NH2:3][CH2:4][CH2:5][CH2:6][NH2:7]>>[NH2:3][CH2:4][CH2:5][CH2:6][NH2:7].[NH:7]1[CH2:4][CH2:5][CH2:6]1

Participants

4

Reactant 2

HCID 4281,3-PropanediamineHCID 178418361HCID 178418361, compound

Product 2

HCID 4281,3-PropanediamineHCID 10422Azetidine

Procedure

A catalyst as described in Example 2 is charged to the reactor and its temperature raised to 150°C under a flow of hydrogen. When a feed of 1,3-diamino propane is passed over the catalyst at LHSV 0.4 at mole ratio H2 :H2N(CH2)3NH2 of 15 a conversion of the feed of 10% at high selectivity to azetidine results.

Workup

  1. additionis charged to the reactor and its temperature

Sources & evidence

ORD record
ord-8765c41acba74ba1b971b875e6ba4db3
Source dataset
uspto-grants-1977_01
Patent number
US04001213

Reaction notes

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