Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1-Aminoanthraquinone → Anthrimide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1-Aminoanthraquinone | HCID 6710 | — |
| 반응물 | Nitrobenzene | HCID 7416 | — |
| 반응물 | Sodium Bicarbonate | HCID 516892 | — |
| 반응물 | 2-Phenyl-6-chloroanthrapyrimidine | HCID 86734347 | — |
| 촉매 | Copper | HCID 23978 | — |
| 생성물 | Anthrimide | HCID 6700 | — |
반응 단계
A mixture of 34.3 parts of 2-phenyl-6-chloroanthrapyrimidine, 24 parts of 1-aminoanthraquinone, 15 parts of sodium bicarbonate, 0.5 part of copper powder and 0.5 part of copper-I chloride in 500 parts of nitrobenzene is stirred under reflux for 4 hours. After cooling, the crystalline dyestuff which has precipitated is filtered off, washed successively with a little nitrobenzene, then with warm alcohol and finally with hot water, and dried in vacuo at 80° - 90°C. 46 parts are obtained of the anthrimide of the formula ##SPC8##
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04001170 |
| 출처 데이터셋 | uspto-grants-1977_01 |
| ORD ID | ord-42969ec707c24f23a5573a9b79d7017e |
| 출처 메모 | uspto-grants-1977_01 |