HRID1414217

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6710

1-Aminoanthraquinone

C14H9NO2

HCID7416

Nitrobenzene

C6H5NO2

HCID516892

Sodium Bicarbonate

CHNaO3

结构：Clc1cc2c(c3cc4ccccc4cc13)CN(c1ccccc1)C=N2

HCID86734347

未命名化合物

PRODUCTS

生成物

结构：O=C1c2ccccc2C(=O)c2c(Nc3cccc4c3C(=O)c3ccccc3C4=O)cccc21

HCID6700

1,1′-Iminobis[9,10-anthracenedione]

C28H15NO4

AUXILIARIES

试剂、催化剂与溶剂

催化剂HCID23978

Copper

PROCEDURE

实验过程

A mixture of 34.3 parts of 2-phenyl-6-chloroanthrapyrimidine, 24 parts of 1-aminoanthraquinone, 15 parts of sodium bicarbonate, 0.5 part of copper powder and 0.5 part of copper-I chloride in 500 parts of nitrobenzene is stirred under reflux for 4 hours. After cooling, the crystalline dyestuff which has precipitated is filtered off, washed successively with a little nitrobenzene, then with warm alcohol and finally with hot water, and dried in vacuo at 80° - 90°C. 46 parts are obtained of the anthrimide of the formula ##SPC8##

WORKUP

后处理

temperatureunder reflux for 4 hours
temperatureAfter cooling
customthe crystalline dyestuff which has precipitated
filtrationis filtered off
washwashed successively with a little nitrobenzene
dry with materialwith warm alcohol and finally with hot water, and dried in vacuo at 80° - 90°C

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-42969ec707c24f23a5573a9b79d7017e
来源数据集: uspto-grants-1977_01
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04001170
来源说明: uspto-grants-1977_01

反应 SMILES

C1(N2C[C:11]3[C:13]4[C:22]([C:23](Cl)=[CH:24][C:10]=3N=C2)=C[C:20]2[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=2)[CH:14]=4)C=CC=CC=1.[NH2:26][C:27]1[C:40]2[C:39](=[O:41])[C:38]3[C:33](=[CH:34][CH:35]=[CH:36][CH:37]=3)[C:32](=[O:42])[C:31]=2[CH:30]=[CH:29][CH:28]=1.[C:43](=[O:46])(O)[O-].[Na+].[N+](C1C=CC=CC=1)([O-])=[O:49]>[Cu]>[CH:35]1[CH:34]=[C:33]2[C:32]([C:31]3[CH:30]=[CH:29][CH:28]=[C:27]([NH:26][C:11]4[C:13]5[C:14]([C:15]6[C:20]([C:43](=[O:46])[C:22]=5[CH:23]=[CH:24][CH:10]=4)=[CH:19][CH:18]=[CH:17][CH:16]=6)=[O:49])[C:40]=3[C:39](=[O:41])[C:38]2=[CH:37][CH:36]=1)=[O:42]