Benzenamine, 2-nitro-N-2-propenyl- → HCID 12000044, compound

HRID 1414802Notes

Reaction equation

HRID 1414802 reaction equation
[N+:1]([C:4]1[CH:13]=[CH:12][CH:11]=[CH:10][C:5]=1[NH:6][CH2:7][CH:8]=[CH2:9])([O-])=O.[H][H]>CO>[CH2:7]([NH:6][C:5]1[CH:10]=[CH:11][CH:12]=[CH:13][C:4]=1[NH2:1])[CH:8]=[CH2:9]

Participants

4

Reactant 2

HCID 10888479Benzenamine, 2-nitro-N-2-propenyl-HCID 178418361HCID 178418361, compound

Product 1

HCID 12000044HCID 12000044, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

35 g of 2-nitro-N-allylaniline in 400 ml of methanol are hydrogenated in the presence of 1.5 g of the catalyst described in Example 6, at 75° C and 100-120 bars of hydrogen, for 1.5 hours, to give N-allyl-o-phenylenediamine. The solution which has been freed from the catalyst by filtration is distilled.

Workup

  1. customdescribed in Example 6, at 75° C

Sources & evidence

ORD record
ord-4dbe217d94af4210bd4fc76dad8be692
Source dataset
uspto-grants-1977_01
Patent number
US04002673

Reaction notes

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