Ethane → 1,1,1,2,3,3-Hexafluoropentane

HRID 1414925Notes

Reaction equation

HRID 1414925 reaction equation
[CH3:1][CH3:2].[F:3][C:4]([F:11])([F:10])[C:5]([F:9])=[C:6]([F:8])[F:7]>>[F:3][C:4]([F:11])([F:10])[CH:5]([F:9])[C:6]([F:8])([F:7])[CH2:1][CH3:2]

Participants

3

Reactant 2

HCID 6324EthaneHCID 8302Hexafluoropropylene

Product 1

HCID 155769681,1,1,2,3,3-Hexafluoropentane

Procedure

When a reaction between ethane and hexafluoropropene was carried out in a 250 ml. Hastalloy-lined autoclave at a temperature of 280° C and under an initial total pressure of 150 atmospheres, a similar yield (76% based on hexafluoropropene consumed) of 1,1,1,2,3,3-hexafluoropentane was obtained.

Workup

  1. customHastalloy-lined autoclave at a temperature of 280° C and under an initial total pressure of 150 atmospheres, a similar yield (76% based on hexafluoropropene consumed) of 1,1,1,2,3,3-hexafluoropentane
  2. customwas obtained

Sources & evidence

ORD record
ord-630d34fac97e49bd84707f22e7d58c04
Source dataset
uspto-grants-1977_01
Patent number
US04002810

Reaction notes

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