M-Xylene → 1-(2,2,3,4,4,4-Hexafluorobutyl)-3-methylbenzene

HRID 1414928Notes

Reaction equation

[F:1][C:2]([F:9])([F:8])[C:3]([F:7])=[C:4]([F:6])[F:5].[C:10]1([CH3:17])[CH:15]=[CH:14][CH:13]=[C:12]([CH3:16])[CH:11]=1>>[F:5][C:4]([F:6])([CH:3]([F:7])[C:2]([F:9])([F:8])[F:1])[CH2:17][C:10]1[CH:11]=[C:12]([CH3:16])[CH:13]=[CH:14][CH:15]=1

Participants

Reactant 2

HCID 7929M-Xylene

HCID 8302Hexafluoropropylene

Product 1

HCID 214860721-(2,2,3,4,4,4-Hexafluorobutyl)-3-methylbenzeneYield 70%

Procedure

Meta-xylene and hexafluoropropene (3:1 molar ratio), heated at 290° for 3 days, gave 3-(2,2,3,4,4,4-hexafluorobutyl)toluene: ##STR14## in 70% yield based on hexafluoropropene consumed.

Sources & evidence

ORD record: ord-fda691ce90be4cc1b366c68659208ac1
Source dataset: uspto-grants-1977_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04002810

Reaction notes

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