Carbon Dioxide → HCID 21484476, compound

HRID 1415321Notes

Reaction equation

HRID 1415321 reaction equation
[CH3:1][O:2][C:3]([CH:5]1[C:13]2[C:8](=[CH:9][C:10]([CH:14]3[CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15]3)=[CH:11][CH:12]=2)[CH2:7][CH2:6]1)=[O:4].C([Li])CCC.[C:26](=[O:28])=[O:27]>CCCCC>[CH3:1][O:2][C:3]([C:5]1([C:26]([OH:28])=[O:27])[C:13]2[C:8](=[CH:9][C:10]([CH:14]3[CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15]3)=[CH:11][CH:12]=2)[CH2:7][CH2:6]1)=[O:4]

Participants

5

Reactant 3

HCID 280Carbon DioxideHCID 53990436HCID 53990436, compoundHCID 178418339Butyllithium

Product 1

HCID 21484476HCID 21484476, compound

Reagents, catalysts & solvents 1

HCID 8003PentaneSolvent

Procedure

melting point 140°-141° C (from pentane), from 10 g of 5-cycloheptyl-1-indanecarboxylic acid methyl ester, 12.8 ml of a 2.6 N solution of butyl-lithium and carbon dioxide.

Sources & evidence

ORD record
ord-a3fc059aac72464bb96e0c0dfdd2c82b
Source dataset
uspto-grants-1977_01
Patent number
US04004026

Reaction notes

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