Hydrochloric Acid → HCID 54351260, compound

HRID 1415486Notes

Reaction equation

HRID 1415486 reaction equation
Cl[C:2]1[CH:7]=[CH:6][C:5]([Cl:8])=[CH:4][CH:3]=1.[Cl:9][C:10]1(Cl)[C:14]([Cl:15])=[C:13]([Cl:16])[C:12]([Cl:17])=[C:11]1[Cl:18].[Cl-:20].[Al+3].[Cl-].[Cl-].Cl>ClC(Cl)=C(Cl)Cl.O>[Cl:20][C:3]1[CH:4]=[C:5]([Cl:8])[CH:6]=[CH:7][C:2]=1[C:14]1([Cl:15])[C:10]([Cl:9])=[C:11]([Cl:18])[C:12]([Cl:17])=[C:13]1[Cl:16]

Participants

7

Reactant 4

HCID 313Hydrochloric AcidHCID 46851,4-DichlorobenzeneHCID 6478HexachlorocyclopentadieneHCID 6451240Aluminum(III) Chloride

Product 1

HCID 54351260HCID 54351260, compound

Reagents, catalysts & solvents 2

HCID 962WaterSolventHCID 31373TetrachloroethyleneSolvent

Procedure

A mixture of 294 grams (2.0 moles) of paradichlorobenzene, 819 grams (3.0 moles) of hexachlorocyclopentadiene, and 15 grams of aluminum chloride, in 300 grams of perchloroethylene was heated at 80°-92° centigrade for two hours during which time a total of 103 grams of hydrogen chloride was evolved. Ten milliliters of water and 20 grams of Superfiltrol absorbent were added and the reaction mixture was stirred at 60° centigrade for 30 minutes and then filtered with suction. The filtrate was distilled at reduced pressure and the fraction boiling at 131°-160° centigrade at 0.5 to 2.3 millimeters of mercury pressure was collected and refractionated through a one foot long heated Vigreux column to give pure 2,4-dichlorophenyl pentachlorocyclopentadiene as a pale yellow viscous oil of boiling point of 146°-147° centigrade at 0.4-0.6 millimeters of mercury.

Workup

  1. filtrationfiltered with suction
  2. distillationThe filtrate was distilled at reduced pressure
  3. customthe fraction boiling at 131°-160° centigrade at 0.5 to 2.3 millimeters of mercury pressure was collected

Sources & evidence

ORD record
ord-23a4a02459454f8b943d510a59191bbd
Source dataset
uspto-grants-1977_01
Patent number
US04005153

Reaction notes

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