Trimethylsilyl cyanide → HCID 21862812, compound

HRID 1415794Notes

Reaction equation

[CH2:1]([O:4][C:5]1[CH:22]=[CH:21][C:8]([CH:9]=[N:10][C:11]2[CH:16]=[CH:15][C:14]([S:17](=[O:20])(=[O:19])[NH2:18])=[CH:13][CH:12]=2)=[CH:7][CH:6]=1)[CH2:2][CH3:3].C[Si]([C:27]#[N:28])(C)C>>[CH2:1]([O:4][C:5]1[CH:22]=[CH:21][C:8]([CH:9]([NH:10][C:11]2[CH:16]=[CH:15][C:14]([S:17](=[O:20])(=[O:19])[NH2:18])=[CH:13][CH:12]=2)[C:27]#[N:28])=[CH:7][CH:6]=1)[CH2:2][CH3:3]

Participants

Reactant 2

HCID 82115Trimethylsilyl cyanide

HCID 21862886HCID 21862886, compound

Product 1

HCID 21862812HCID 21862812, compound

Procedure

Following a procedure similar to that described in Example 1(ii), but using N-(4-propoxybenzylidene)-4-sulfamoylaniline [prepared as described in step (i) above] and trimethylsilyl cyanide as starting materials, the title compound was obtained as a pale yellow powder (yield 80%).

Sources & evidence

ORD record: ord-7a3b65d2f98d484a89f700c8a7a5d57a
Source dataset: uspto-grants-1999_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05908858

Reaction notes

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