Trimethylsilyl cyanide → HCID 21862777, compound

HRID 1415797Notes

Reaction equation

[CH3:1][O:2][C:3]1[CH:20]=[CH:19][C:6]([CH:7]=[N:8][C:9]2[CH:14]=[CH:13][C:12]([S:15](=[O:18])(=[O:17])[NH2:16])=[CH:11][CH:10]=2)=[CH:5][C:4]=1[CH3:21].C[Si]([C:26]#[N:27])(C)C>>[CH3:1][O:2][C:3]1[CH:20]=[CH:19][C:6]([CH:7]([NH:8][C:9]2[CH:10]=[CH:11][C:12]([S:15](=[O:17])(=[O:18])[NH2:16])=[CH:13][CH:14]=2)[C:26]#[N:27])=[CH:5][C:4]=1[CH3:21]

Participants

Reactant 2

HCID 82115Trimethylsilyl cyanide

HCID 21862874HCID 21862874, compound

Product 1

HCID 21862777HCID 21862777, compound

Procedure

Following a procedure similar to that described in Example 1(ii), but using N-(4-methoxy-3-methylbenzylidene)-4-sulfamoylaniline [prepared as described in step (i) above] and trimethylsilyl cyanide as starting materials, the title compound was obtained as a white powder (yield 63%).

Sources & evidence

ORD record: ord-a7ecd2cfbaa14569925551e6a141a464
Source dataset: uspto-grants-1999_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05908858

Reaction notes

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