Trimethylsilyl cyanide → HCID 21862890, compound

HRID 1415833Notes

Reaction equation

[CH2:1]([S:3][C:4]1[CH:21]=[CH:20][C:7]([N:8]=[CH:9][C:10]2[CH:15]=[CH:14][C:13]([S:16](=[O:19])(=[O:18])[NH2:17])=[CH:12][CH:11]=2)=[CH:6][CH:5]=1)[CH3:2].C[Si]([C:26]#[N:27])(C)C>>[CH2:1]([S:3][C:4]1[CH:21]=[CH:20][C:7]([NH:8][CH:9]([C:10]2[CH:15]=[CH:14][C:13]([S:16](=[O:19])(=[O:18])[NH2:17])=[CH:12][CH:11]=2)[C:26]#[N:27])=[CH:6][CH:5]=1)[CH3:2]

Participants

Reactant 2

HCID 82115Trimethylsilyl cyanide

HCID 21862799HCID 21862799, compound

Product 1

HCID 21862890HCID 21862890, compound

Procedure

Following a procedure similar to that described in Example 1(ii), but using 4-ethylthio-N-(4-sulfamoylbenzylidene)aniline [prepared as described in step (i) above] and trimethylsilyl cyanide as starting materials, the title compound was obtained as a yellow powder (yield 100%).

Sources & evidence

ORD record: ord-960a035d867c415e8393f7b9619c4bca
Source dataset: uspto-grants-1999_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05908858

Reaction notes

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