Acetylacetone → Cerium nitrate

HRID 1417133Notes

Reaction equation

C(CC(=O)C)(=O)C.O.O.O.O.O.O.[N+:14]([O-:17])([O-:16])=[O:15].[Ce+3:18].[N+:19]([O-:22])([O-:21])=[O:20].[N+:23]([O-:26])([O-:25])=[O:24]>>[N+:14]([O-:17])([O-:16])=[O:15].[Ce+3:18].[N+:19]([O-:22])([O-:21])=[O:20].[N+:23]([O-:26])([O-:25])=[O:24]

Participants

Reactant 2

HCID 31261Acetylacetone

HCID 16211466Cerous nitrate hexahydrate

Product 1

HCID 24948Cerium nitrate

Conditions

Temperature: 90 °C

Procedure

3 moles of acetylacetone was added to 1 mole of cerium nitrate hexahydrate, followed by treatment by heating to 90° C. with agitation for 1 hour. The resultant solution was provided as a stock solution for cerium nitrate. This contained 23.2% of CeO2 as solids.

Sources & evidence

ORD record: ord-36e459d44ff941b0ab5c70cf9c54ab1e
Source dataset: uspto-grants-1999_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05876854

Reaction notes

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