HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzaldehyde → 1-Nitro-2-phenylethane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzaldehyde | HCID 240 | — |
| Reactant | O-Phenylenediamine | HCID 7243 | — |
| Reactant | beta-nitrostyrene, (E)- | HCID 5284459 | — |
| Reactant | HCID 178461471 | HCID 178461471 | — |
| Product | 1-Nitro-2-phenylethane | HCID 80208 | 95% |
Reaction Steps
Isomer B: (±) (trans) 4-methyl-5-(phenylmethyl)pyrrolidin-2-imine, monohydrochloride ##STR224## 219 A) trans-b-Nitrostyrene (63.0 g, 0.42 mole) was reacted with benzaldehyde (53.4 g, 0.5 mole) and 1,2-diaminobenzene (54.4 g, 0.5 mole) according to the procedure of Chikashita et. al. (Synth. Commun. 1985, 15 (6), 527) to yield (2-nitroethyl)benzene (60.0 g, 95%) as a yellow oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05883251 |
| Source dataset | uspto-grants-1999_03 |
| ORD ID | ord-3fd5581b16a44858aaa8400d92f22a12 |
| Source note | uspto-grants-1999_03 |