HuagongsheHuagongshe Chemistry Print Report · For research reference only
(4-(Decyloxy)phenyl)boronic acid → 2-(4-Decyloxyphenyl)-9,9,10,10-tetrafluoro-7-butyl-9,10-dihydrophenanthrene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (4-(Decyloxy)phenyl)boronic acid | HCID 10612601 | — |
| Reactant | 9,9,10,10-Tetrafluoro-2-bromo-7-butyldihydrophenanthrene | HCID 54442732 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Product | 2-(4-Decyloxyphenyl)-9,9,10,10-tetrafluoro-7-butyl-9,10-dihydrophenanthrene | HCID 54561094 | — |
Reaction Steps
From 9,9,10,10-tetrafluoro-2-bromo-7-butyldihydrophenanthrene and 4-decyloxyphenylboronic acid by means of palladium-catalyzed Suzuki coupling (in analogy to Acc. Chem. Res. 1982, 15, 178). The crude product is purified by column chromatography.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05888422 |
| Source dataset | uspto-grants-1999_03 |
| ORD ID | ord-18bcf341992a40ba9379444e544c305c |
| Source note | uspto-grants-1999_03 |