Triethoxysilane → HCID 22617099, compound

HRID 1419672Notes

Reaction equation

HRID 1419672 reaction equation
[CH2:1]([O:3][SiH:4]([O:8][CH2:9][CH3:10])[O:5][CH2:6][CH3:7])[CH3:2].[CH2:11]([N:13]([C:20]1[CH:27]=[CH:26][C:23]([CH:24]=[CH2:25])=[CH:22][CH:21]=1)[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1)[CH3:12]>C1(C)C=CC=CC=1>[CH2:11]([N:13]([C:20]1[CH:21]=[CH:22][C:23]([CH2:24][CH2:25][Si:4]([O:8][CH2:9][CH3:10])([O:5][CH2:6][CH3:7])[O:3][CH2:1][CH3:2])=[CH:26][CH:27]=1)[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1)[CH3:12]

Participants

4

Reactant 2

HCID 13830TriethoxysilaneHCID 22617095HCID 22617095, compound

Product 1

HCID 22617099HCID 22617099, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent2×

Procedure

Into a three-necked flask, 40 ml of toluene, 9.9 g (60 mmol) of triethoxysilane and 0.018 mmol of diplatinum (0) tris(tetramethyldivinyldisiloxane)in toluene were placed, and 20 ml of a toluene solution containing 7.6 g of 4-(N-ethyl-N-phenylamino)styrene was added dropwise with stirring at room temperature. After the addition was completed, the mixture was stirred at 70° C. for 3 hours, and then the solvent was removed under reduced pressure to obtain oily pale yellow 4-(N-ethyl-N-phenylamino)-[2-(triethoxysilyl)ethyl]benzene in an amount of 7.8 g.

Workup

  1. additionwas added dropwise
  2. additionAfter the addition
  3. stirringthe mixture was stirred at 70° C. for 3 hours
  4. customthe solvent was removed under reduced pressure

Sources & evidence

ORD record
ord-52e1396cb6b24afd8d448e228dfdc650
Source dataset
uspto-grants-1999_03
Patent number
US05888690

Reaction notes

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