m-Chloroperbenzoic acid → HCID 18781977, compound

HRID 1420534Notes

Reaction equation

HRID 1420534 reaction equation
[CH3:1][S:2][CH:3]1[N:6]([CH2:7][CH2:8][CH2:9][C:10]([C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=2)=[O:11])[C:5](=[O:18])[CH2:4]1.C1C=C(Cl)C=C(C(OO)=[O:27])C=1>>[CH3:1][S:2]([CH:3]1[N:6]([CH2:7][CH2:8][CH2:9][C:10]([C:12]2[CH:13]=[CH:14][CH:15]=[CH:16][CH:17]=2)=[O:11])[C:5](=[O:18])[CH2:4]1)=[O:27]

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 18781948HCID 18781948, compound

Product 1

HCID 18781977HCID 18781977, compoundYield 89%

Procedure

Treatment of 4-methylthio-1-(4-phenyl-4-oxobutyl)azetidin-2-one (0.29 g, 1.09 mmol)with mCPBA as described in Example 2 gave the title compound as a yellow oil (0.27 g, 89%),

Sources & evidence

ORD record
ord-73613515b3d145d495012e09f3757abb
Source dataset
uspto-grants-2000_06
Patent number
US06071899

Reaction notes

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