m-Chloroperbenzoic acid → HCID 18782048, compound

HRID 1420543Notes

Reaction equation

HRID 1420543 reaction equation
[F:1][C:2]1[CH:7]=[CH:6][C:5]([CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][NH:14][C:15](=[O:32])[CH2:16][N:17]2[CH:20]([S:21][CH2:22][CH2:23][CH2:24][C:25]([O:27][CH2:28][CH:29]=[CH2:30])=[O:26])[CH2:19][C:18]2=[O:31])=[CH:4][CH:3]=1.C1C=C(Cl)C=C(C(OO)=[O:41])C=1>>[F:1][C:2]1[CH:3]=[CH:4][C:5]([CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][NH:14][C:15](=[O:32])[CH2:16][N:17]2[CH:20]([S:21]([CH2:22][CH2:23][CH2:24][C:25]([O:27][CH2:28][CH:29]=[CH2:30])=[O:26])=[O:41])[CH2:19][C:18]2=[O:31])=[CH:6][CH:7]=1

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 18782043HCID 18782043, compound

Product 1

HCID 18782048HCID 18782048, compoundYield 21%

Procedure

Treatment of N-[6-(4-Fluorophenyl)hexyl]-[4-(3-allyloxycarbonylpropyl)thio-2-oxo-azetidin-1-yl]-acetamide with mCPBA as described for Example 17 gave thetitle compound as a white crystalline solid, m.p. 95-96° C., 21% yield

Workup

  1. customgave thetitle compound as a white crystalline solid, m.p. 95-96° C., 21% yield

Sources & evidence

ORD record
ord-70d2aaf84a1e46ba93e4752e4e15dba6
Source dataset
uspto-grants-2000_06
Patent number
US06071899

Reaction notes

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