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HRID1420869

反应详情

EQUATION

反应方程式

HRID 1420869 的结构方程式

REACTANTS

反应物

1
结构：CCOC(=O)C=C1CC(C)(C)CC(C)(C)C1
HCID15307456

Ethyl (3,3,5,5-tetramethylcyclohexylidene)acetate

C14H24O2

PRODUCTS

生成物

1
结构：CCOC(=O)CC1CC(C)(C)CC(C)(C)C1
HCID18783146

未命名化合物

收率 95%

AUXILIARIES

试剂、催化剂与溶剂

2
结构：[Pd]
催化剂HCID23938

Palladium

Pd

结构：CCO
溶剂HCID702

Ethanol

C2H6O

PROCEDURE

实验过程

Ethyl 3,3,5,5-tetramethylcyclohexylideneacetate (7) (4.48 g, 20 mmol) in ethanol (100 ml) was hydrogenated over 10% Pd/C (0.22 g, 5 wt. %) at 10 atm for 18 h. Filtration through Celite™ and evaporation afforded 4.28 g (95%) of 8 as an oil.

WORKUP

后处理

  1. filtrationFiltration
  2. customthrough Celite™ and evaporation