Trifluoroacetic acid → HCID 56632868, compound

HRID 1421201Notes

Reaction equation

HRID 1421201 reaction equation
C([O:5][C:6](=[O:45])[C@H:7]([CH2:26][S:27][C:28](=[O:44])[CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH3:43])[NH:8][C:9](=[O:25])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])(C)(C)C.FC(F)(F)C(O)=O>>[C:9]([NH:8][C@H:7]([C:6]([OH:45])=[O:5])[CH2:26][S:27][C:28](=[O:44])[CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH3:43])(=[O:25])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24]

Participants

3

Reactant 2

HCID 6422Trifluoroacetic acidHCID 56632483HCID 56632483, compound

Product 1

HCID 56632868HCID 56632868, compound

Procedure

N,S-Dipalmitoylcysteine tert.-butyl ester (1 g, 1.5 mmol) is treated with anhydrous trifluoroacetic acid for 1 h. The latter is then removed in a rotary evaporator under high vacuum, and the residue is taken up in tert.-butanol and freeze-dried.

Workup

  1. customThe latter is then removed in a rotary evaporator under high vacuum
  2. customfreeze-dried

Sources & evidence

ORD record
ord-3c5ecd90890948b7af586a7a3d27d091
Source dataset
uspto-grants-2000_06
Patent number
US06074650

Reaction notes

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