Phosphorus oxide (P4O10) → HCID 18706217, compound

HRID 1421854Notes

Reaction equation

HRID 1421854 reaction equation
[O:1]=[P:2]12[O:13]P3(OP(OP(O3)([O:9]1)=O)(=O)[O:3]2)=O.C[Si](C)(C)O[Si](C)(C)C.[CH2:24]([S:36][CH2:37][CH:38]([O:41][CH2:42][CH2:43][CH2:44]CCCCCCC)[CH2:39]O)[CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH3:35]>N1C=CC=CC=1>[CH2:24]([S:36][CH:37]([CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[CH:38]([O:41][CH2:42][CH2:43][CH2:44][O:3][P:2](=[O:1])([OH:13])[OH:9])[CH3:39])[CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH3:35]

Participants

5

Reactant 3

HCID 14812Phosphorus oxide (P4O10)HCID 24764HexamethyldisiloxaneHCID 118258831-Propanol, 2-(decyloxy)-3-(dodecylthio)-

Product 1

HCID 18706217HCID 18706217, compound

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Conditions

Temperature
100 °C

Procedure

A suspension of 4.26 g P4O10 in 60 ml absolute pyridine was admixed at room temperature with 13 ml hexamethyldisiloxane and heated to 100° C. for 1 hour. It was then slightly cooled, admixed with 25 g 3-dodecylmercapto-2-decyloxy-1-propanol and heated for a further 2.5 hours to 100° C.

Workup

  1. temperatureIt was then slightly cooled
  2. temperatureheated for a further 2.5 hours to 100° C.

Sources & evidence

ORD record
ord-7feecf3472544bf299f262297310d1a6
Source dataset
uspto-grants-2000_06
Patent number
US06080734

Reaction notes

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