関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 3,6,9,15-Tetraazabicyclo(9.3.1)pentadeca-1(15),11,13-triene | HCID 586675 | — |
| 反応物 | Acetonitrile--water (1/1) | HCID 18373917 | — |
| 反応物 | HCID 22608817 | HCID 22608817 | — |
| 生成物 | HCID 58232819 | HCID 58232819 | — |
反応手順
10 mg of 3,6,9,15-tetraazabicyclo[9.3.1]pentadeca-1(14),11(15),12-triene (48.5 μmol) are dissolved in a water-acetonitrile mixture (170 μl of acetonitrile and 7 μl of water). After the addition of 10 μl of TEA (1.4 eq), the mixture is heated to 50° C. and then 13 mg of ethyl bromoglutarate (1 eq) are added. The medium is stirred at 50° C. for 18 h.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US08926945B2 |
|---|
| 出典データセット | uspto-grants-2015_01 |
|---|
| ORD ID | ord-0f1820f999644b6f8a786a75578573de |
|---|
| 出典メモ | uspto-grants-2015_01 |
|---|
