Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
4-O-benzyl-3,6-di-O-acetyl-D-glucose → 3,6-di-O-acetyl-D-glucose
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 4-O-benzyl-3,6-di-O-acetyl-D-glucose | HCID 86654839 | — |
| 반응물 | HCID 178418361 | HCID 178418361 | — |
| 촉매 | Palladium | HCID 23938 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | 3,6-di-O-acetyl-D-glucose | HCID 86654840 | — |
반응 단계
Degussa 10% Pd/C (50% wet) (0.4 g) was added to the solution of 4-O-benzyl-3,6-di-O-acetyl-D-glucose (5 mmol) in ethanol (50 mL). Obtained mixture was hydrogenated at room temperature using Paar apparatus with hydrogen (45 psi) After 12 hr reaction was completed (TLC), catalyst was filtered off and the solvent was evaporated to give a crude product. Product was purified by column chromatography (SilicaGel 60 Merck), using hexanes:ethyl acetate as eluent.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08927506B2 |
| 출처 데이터셋 | uspto-grants-2015_01 |
| ORD ID | ord-a3b7de27c6b74290ae0a91850643d512 |
| 출처 메모 | uspto-grants-2015_01 |