HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl Acetate → HCID 57660952, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl Acetate | HCID 8857 | — |
| Reactant | Cesium carbonate | HCID 10796 | — |
| Reactant | 1,1'-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(1,1-diphenylphosphine) | HCID 636044 | — |
| Reactant | HCID 16678135 | HCID 16678135 | — |
| Reactant | HCID 57660929 | HCID 57660929 | — |
| Catalyst | HCID 11072516 | HCID 11072516 | — |
| Product | HCID 57660952 | HCID 57660952 | — |
Reaction Steps
45 mg (0.074 mmol) of (8), 50 mg (0.123 mmol) of (7), 48 mg (0.148 mmol) of Cs2CO3, 16 mg (0.024 mmol) of Pd(dba)2-CHCl3 and 43 mg (0.074 mmol) of Xantphos were heated under argon for 3 hours. After diluting with 50 ml ethyl acetate and washing two times with saturated aqueous NaHCO3 and one time with brine the solution was dried over Na2SO4 and concentrated in vacuo. 70 mg of crude (15) were obtained as yellow foam.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08927534B2 |
| Source dataset | uspto-grants-2015_01 |
| ORD ID | ord-1b4cad4e707e4324bc55a94e97f19380 |
| Source note | uspto-grants-2015_01 |