2,6-Naphthalenedicarboxylic acid → HCID 86699515, compound

HRID 1425616Notes

Reaction equation

HRID 1425616 reaction equation
[CH:1]1[C:10]2[C:5](=[CH:6][C:7]([C:11]([OH:13])=[O:12])=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[C:14]([OH:16])=[O:15].O.[OH-].[Li+:19]>CO>[CH:1]1[C:10]2[C:5](=[CH:6][C:7]([C:11]([O-:13])=[O:12])=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[C:14]([O-:16])=[O:15].[Li+:19].[Li+:19]

Participants

4

Reactant 2

HCID 143572,6-Naphthalenedicarboxylic acid2×HCID 168937Lithium hydroxide, monohydrate3×

Product 1

HCID 86699515HCID 86699515, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Lithium 2,6-naphthalenedicarboxylate was synthesized by repeating the procedure of Experimental Example 1. The starting materials used were 2,6-naphthalenedicarboxylic acid and lithium hydroxide monohydrate (LiOH.H2O). Methanol (100 mL) was added to lithium hydroxide monohydrate (0.556 g), and it was stirred. After the lithium hydroxide monohydrate was dissolved, 2,6-naphthalenedicarboxylic acid (1.0 g) was added, and it was stirred for one hour. After stirring, the solvent was removed, and the residue was dried in vacuo at 150° C. for 16 hours to yield a white powder sample.

Workup

  1. stirringit was stirred for one hour
  2. stirringAfter stirring
  3. customthe solvent was removed
  4. customthe residue was dried in vacuo at 150° C. for 16 hours
  5. customto yield a white powder sample

Sources & evidence

ORD record
ord-a3d545fb8ca2468088093e5e3f184646
Source dataset
uspto-grants-2015_01
Patent number
US08932758B2

Reaction notes

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