Bromobenzene → HCID 11333310, compound

HRID 1428435Notes

Reaction equation

HRID 1428435 reaction equation
[Br:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:8](Cl)(=[O:11])[CH:9]=[CH2:10].[Cl-].[Al+3].[Cl-].[Cl-]>ClCCl>[C:8]([C:5]1[CH:6]=[CH:7][C:2]([Br:1])=[CH:3][CH:4]=1)(=[O:11])[CH:9]=[CH2:10]

Participants

5

Reactant 3

HCID 7961BromobenzeneHCID 13140Acryloyl chlorideHCID 6451240Aluminum(III) Chloride

Product 1

HCID 11333310HCID 11333310, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

Bromobenzene (0.5 mL), acryloyl chloride (110 mg), and aluminium chloride (160 mg) were reacted in dichloromethane (1.5 mL) at from 0° C. to room temperature for 4 hours. The resultant was treated in the same manner as described in Example 1 to obtain the title compound (1207.0 mg).

Workup

  1. additionThe resultant was treated in the same manner

Sources & evidence

ORD record
ord-b85cabe90bc24e8299d83d37490b7081
Source dataset
uspto-grants-2015_01
Patent number
US08937091B2

Reaction notes

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