Methacryloyl chloride → HCID 86673227, compound

HRID 1428438Notes

Reaction equation

HRID 1428438 reaction equation
[CH3:1][O:2][C:3]1[CH:4]=[C:5]([Br:9])[CH:6]=[CH:7][CH:8]=1.[C:10](Cl)(=[O:14])[C:11]([CH3:13])=[CH2:12].[Cl-].[Al+3].[Cl-].[Cl-]>ClCCl>[Br:9][C:5]1[CH:6]=[CH:7][C:8]([C:10](=[O:14])[C:11]([CH3:13])=[CH2:12])=[C:3]([O:2][CH3:1])[CH:4]=1

Participants

5

Reactant 3

HCID 13528Methacryloyl chlorideHCID 169713-BromoanisoleHCID 6451240Aluminum(III) Chloride

Product 1

HCID 86673227HCID 86673227, compoundYield 44.7%

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

3-methoxybromobenzene (238 mg), methacryloyl chloride (110 mg), and aluminium chloride (160 mg) were reacted in dichloromethane (1.5 mL) at from 0° C. to room temperature for 4 hours. The resultant was treated in the same manner as described in Example 1 to obtain the title compound (120 mg).

Workup

  1. additionThe resultant was treated in the same manner

Sources & evidence

ORD record
ord-ba11a7992abc48e7a964f49c41187ae0
Source dataset
uspto-grants-2015_01
Patent number
US08937091B2

Reaction notes

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